There are three ways to on-board AWS Usage accounts.
Why this matters: Manual and CloudFormation trade off effort against scale — Manual suits onboarding a single account by hand, while CloudFormation is built for onboarding many accounts at once (bulk) or automating a repeatable single-account setup (individual), rather than clicking through the same steps every time.
Manual Onboarding
AWS Member Account Manual Onboarding
Cloud Formation Based Onboarding (Bulk Onboarding)
AWS Member Account CloudFormation Onboarding (Org)