Steps to onboard AWS account from setup page:
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Click on AWS Provider
If you want to onboard manually click on 'Or connect manually'
Automated Onboarding
Faster option — uses a CloudFormation template that sets up the required cross-account role for you.
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Follow the following steps by using ref link
Ref link: Cloud Formation Based Onboarding
Manual Onboarding
Takes a bit longer, but walks through creating the IAM role and permissions yourself — useful if your security team wants to review each permission before it's granted.
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Follow the following steps by using ref link
Ref Link : Manual Onboarding